Studies of the Kolbe Electrolytic Synthesis. II. The Preparation of Trialkylacetic Esters and Acids1

L Eberson

Index: Eberson,L. Journal of Organic Chemistry, 1962 , vol. 27, p. 3706 - 3708

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Citation Number: 7

Abstract

Methods for the preparation of trialkylacetic acids include carbonation of Grignard reagent^,^^^ alkylation of esters, ketones, and nitrile^,^-^ hydrogenation of alkenyldialkylacetic e~ ters,~,'~ reaction of carbon monoxide under pressure or in situ with olefins, alcohols, alkyl chlorides, or esters, ll oxidation of ketones and olefin^,^**^^ aiid rearrangement of at-bromo ketones. 14 These methods often suffer from the ...