Journal of Organometallic Chemistry

Photochemically generated silicon carbon double-bonded intermediates: VII. A new route to silaethene derivatives from 1-alkenyldisilanes

M Ishikawa, T Fuchikami, M Kumada

Index: Ishikawa,M. et al. Journal of Organometallic Chemistry, 1978 , vol. 149, p. 37 - 48

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Citation Number: 39

Abstract

Abstract Photolysis of 1-alkenyldisilanes, with one exception, afforded silaethene type of silicon—carbon intemediates via photorearrangement of a silyl group to the carbon atom of a vinyl substituent. These intermediates reacted with methanol and methanol-d 1 to give the corresponding methoxysilanes in high yields. With E-2-phenylethenylpentamethyldisilane, UV-irradiation in the presence of methanol gave 1-methoxydimethylsilyl-1-trimethylsilyl-2- ...