Heterocyclic Vinyl Ethers. XII. The Synthesis of Arylmercaptoacetylenes and a New Cleavage Reaction of Benzo-1, 4-dithiadiene1, 2

WE Parham, PL Stright

Index: Parham; Stright Journal of the American Chemical Society, 1956 , vol. 78, p. 4783,4785

Full Text: HTML

Citation Number: 35

Abstract

I SI11 i SIT bility we repeated the reaction using excess n-butyllithium and one equivalent of dimethyl sulfate.-1 vigorous reaction occurred, and the neutral product (46Yc yield), thus obtained, was subsequently identified as the hitherto unknown 1-(n-butylthio)-2- methylthiobenzene (XIII). This product was characterized by conversion to sulfone XI\'and the sulfonyl chlo-The structures of XIII. XIV and XV were established by their independent ...

Related Articles:

Prototropic rearrangement of 2-propynyl (methyl) amino, 2-propynyloxy, and 2-propynylsulfanyl derivatives of hetarenes under conditions of phase-transfer catalysis: …

[Rubina; Fleisher; Abele; Popelis; Lukevits Russian Journal of Organic Chemistry, 2003 , vol. 39, # 7 p. 963 - 967]

Prototropic rearrangement of 2-propynyl (methyl) amino, 2-propynyloxy, and 2-propynylsulfanyl derivatives of hetarenes under conditions of phase-transfer catalysis: …

[Rubina; Fleisher; Abele; Popelis; Lukevits Russian Journal of Organic Chemistry, 2003 , vol. 39, # 7 p. 963 - 967]

Studies related to the total synthesis of the sesquiterpene core of the pyrrolobenzoxazine natural products CJ-12662 and CJ-12663

[Commandeur, Malgorzata; Commandeur, Claude; Paolis, Michael De; Edmunds, Andrew J.F.; Maienfisch, Peter; Ghosez, Leon Tetrahedron Letters, 2009 , vol. 50, # 26 p. 3359 - 3362]

Pyrolysis of α-acyl, α,-thio phosphoranes→ thioacetylenes

[Braga, Antonio L.; Comasseto, Joao V.; Petragnani, Nicola Tetrahedron Letters, 1984 , vol. 25, # 11 p. 1111 - 1114]

Selenium heterocycles. XXXV. Synthesis and pyrrolysis of aryloxy??, arylthio??, and arylseleno??1, 2, 3??selenadiazoles

[Shafiee, A.; Toghraie, S.; Aria, F.; Mortezaei-Zandjani, G. Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 1305 - 1308]

More Articles...