Absolute rate constants for hydrocarbon autoxidation. 30. On the self-reaction of the α-cumylperoxy radical in solution

JA Howard, JE Bennett…

Index: Howard, J. A.; Bennett, J. E.; Brunton, G. Canadian Journal of Chemistry, 1981 , vol. 59, p. 2253 - 2260

Full Text: HTML

Citation Number: 29

Abstract

Although it is generally accepted that the self-reaction of cumylperoxy radicals is a second- order process, recent reports have cast doubt on the overall validity of this assumption. Therefore we have reinvestigated some aspects of the self-reaction to clarify the kinetic and mechanistic features. Our product studies are entirely consistent with the accepted mechanism for the self-reaction of cumylperoxy radicals and no evidence was obtained for ...

Related Articles:

Characterization, via ESR spectroscopy, of radical intermediates in the photooxidation of arylcarbinols by ceric ammonium nitrate

[Grossi, Loris; Strazzari, Samantha Journal of Organic Chemistry, 2000 , vol. 65, # 9 p. 2748 - 2754]

Deuterium kinetic isotope effects in homogeneous decatungstate catalyzed photooxygenation of 1, 1-diphenylethane and 9-methyl-9H-fluorene: evidence for a …

[Lykakis, Ioannis N.; Orfanopoulos, Michael Tetrahedron Letters, 2005 , vol. 46, # 45 p. 7835 - 7839]

Titanium (IV) tert-butoxide-tert-butyl hydroperoxide system as oxidant for CH bonds in hydrocarbons and oxygen-containing compounds

[Stepovik; Gulenova; Martynova Russian Journal of General Chemistry, 2005 , vol. 75, # 4 p. 507 - 513]

Oxidizing properties of the tert-butyl hydroperoxide-tetra-tert-butoxychromium system

[Stepovik; Potkina; Poddelskii Russian Journal of General Chemistry, 2013 , vol. 83, # 11 p. 2005 - 2017 Zh. Obshch. Khim., 2013 , vol. 83, # 11 p. 1805 - 1818,14]

Absolute rate constants for hydrocarbon autoxidation. 32. On the self-reaction of 1, 1-diphenylethylperoxyl in solution

[Howard, J. A.; Chenier, J. H. B.; Yamada, T. Canadian Journal of Chemistry, 1982 , vol. 60, p. 2566 - 2572]

More Articles...