Oxidizing properties of the tert-butyl hydroperoxide-tetra-tert-butoxychromium system

LP Stepovik, AY Potkina, AI Poddelskii

Index: Stepovik; Potkina; Poddelskii Russian Journal of General Chemistry, 2013 , vol. 83, # 11 p. 2005 - 2017 Zh. Obshch. Khim., 2013 , vol. 83, # 11 p. 1805 - 1818,14

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Abstract

Abstract tert-Butyl hydroperoxide reacts with the tetra-tert-butoxychromium by oxidizing the latter to chromyl CrV= O (C 6 H 6, 20° C). At t-BuOOH-Cr (OBu-t) 4 ratio of 2: 1 or higher, oxygen is released. The occuring processes include the formation of chromium-containing peroxides and peroxytrioxydes. The t-BuOOH-Cr (OBu-t) 4 system oxidizes aromatic hydrocarbons of various structures (anthracene, 9, 10-dimethylanthracene, 1, 1- ...

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