Researches on pyrimidines. CXV. Alkylation on nitrogen of the pyrimidine cycle by application of a new technique involving molecular rearrangements

GE Hilbert, TB Johnson

Index: Hilbert; Johnson Journal of the American Chemical Society, 1930 , vol. 52, p. 2001,2006

Full Text: HTML

Citation Number: 105

Abstract

That the lactim ethers I will undergo rearrangements to their isomeric and stable Zactam configurations I1 has been known for a long time. These transformations are not reversible and are brought about by the application of heat or through the influence of special catalytic agents, and have been observed to take place in both the acyclic and cyclic series of organic compounds.*.

Related Articles:

Photodetachment of zwitterions: Probing intramolecular coulomb repulsion and attraction in the gas phase using pyridinium dicarboxylate anions

[Kristiansen, Marianne; Eriksen, Jens; Joergensen, Karl Anker Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 1 p. 101 - 103]

HSAB-driven chemoselective N 1-alkylation of pyrimidine bases and their 4-methoxy-or 4-acetylamino-derivatives

[Gambacorta, Augusto; Tofani, Daniela; Loreto, Maria Antonietta; Gasperi, Tecla; Bernini, Roberta Tetrahedron, 2006 , vol. 62, # 29 p. 6848 - 6854]

More Articles...