Aliphatic semidiones. 44. Spin probes derived from dithiols

GA Russell, WC Law, M Zaleta

Index: Russell,G.A.; Law,W.C.; Zaleta,M. Journal of the American Chemical Society, 1985 , vol. 107, p. 4175

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Citation Number: 29

Abstract

Abstract: Mono-and dithio-1, 2-semidiones have been prepared. The dithiosemidiones have lower uDIH and higher g values than the semidiones. The dithiete, 1, 4-dithiin, and 2, 3- dihydro-l, 4-dithiin radical cations derived from bicyclo [2.2. l] hept-2-ene-2, 3-dithiol have been prepared and demonstrated to possess a strong W-plan interaction with the'Janti-and 5, 6,,-hydrogen atoms as expected for a symmetric SOMO. The radical cation of 2, 3- ...

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