Reactions of Atoms and Free Radicals in Solution. I. A Study of the Substitution of Hydrogen on an Asymmetric Carbon Atom—The Chlorination of Primary Active Amyl …

HC Brown, MS Kharasch, TH Chao

Index: Brown; Kharasch; Chao Journal of the American Chemical Society, 1940 , vol. 62, p. 3437 - 3439

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Citation Number: 21

Abstract

(12) Since no attempt was made to isolate or identify any of the products of the reaction with the exception of lithium borohydride, it is possible that the excess aluminum borohydride and the triethylaluminum were not present as such in the volatile products of the reaction. Mixtures of the compounds of the type CzHaAI-iBH4) z would yield the same analytical results. tion of diborane on ethyllithium. Its physical and chemical properties suggest that ...