Journal of Fluorine Chemistry

Fluorinations with complex metal fluorides. Part 7. Fluorinations of the methyl pyridines with caesium tetrafluorocobaltate

RG Plevey, RW Rendell, JC Tatlow

Index: Plevey, Raymond G.; Rendell, Richard W.; Tatlow, John Colin Journal of Fluorine Chemistry, 1982 , vol. 21, p. 265 - 286

Full Text: HTML

Citation Number: 9

Abstract

Abstract 4-Methylpyridine passed over caesium tetrafluorocobaltate at 330–340 gave tridecafluoro (1, 3-dimethylpyrrolidine)(1) and its 3-difluoromethyl analogue (2), together with a range of polyfluoro-4-picolines (4–10) with− CF 3,− CHF 2 or− CH 2 F groups in the 4- position. 3-Methylpyridine similarly gave 1 and its 1, 2-isomer (11) together with several polyfluoro-3-picolines (14–18). 2-Methylpyridine at 270 gave tridecafluoro (1- ...

Related Articles:

Investigations on the product distribution pattern during the electrochemical fluorination of 2-fluoropyridine and pyridine

[Sartori; Velayutham; Ignat'ev; Noel Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 31 - 36]

Investigations on the product distribution pattern during the electrochemical fluorination of 2-fluoropyridine and pyridine

[Sartori; Velayutham; Ignat'ev; Noel Journal of Fluorine Chemistry, 1998 , vol. 87, # 1 p. 31 - 36]

The electrochemical fluorination of nitrogen-containing carboxylic acids. Fluorination of methyl esters of 3-dialkylamino propionic acids

[Abe, Takashi; Hayashi, Eiji; Fukaya, Haruhiko; Hayakawa, Yoshio; Baba, Hajime; et al. Journal of Fluorine Chemistry, 1992 , vol. 57, p. 101 - 111]

Highly fluorinated heterocycles. Part XVI. Polyfluorinated derivatives of 1-methylpyrrolidine, 1-methylpyrrol-3-ine and 1-methylpyrrole

[Coe, Paul L.; Holton, Andrew G.; Sleigh, John H.; Smith, Peter; Tatlow, John Colin Journal of Fluorine Chemistry, 1983 , vol. 22, p. 287 - 298]

Electrochemical fluorination of (N, N-dialkylamino) alcohols

[Abe, Takashi; Fukaya, Haruhiko; Hayashi, Eiji; Ono, Taizo; Nishida, Masakazu; Soloshonok, Irina; Okuhara, Kunio Journal of Fluorine Chemistry, 1999 , vol. 97, # 1-2 p. 229 - 237]

More Articles...