Syntheses of dibenzo [c, e][1, 2] diselenin and related novel chalcogenide heterocyclic compounds
S Murata, T Suzuki, A Yanagisawa…
Index: Murata, Shizuaki; Suzuki, Toshiyasu; Yanagisawa, Akira; Suga, Seiji Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 2 p. 433 - 438
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Citation Number: 18
Abstract
Abstract Reaction of 2, 2′-dilithio-1, 1′-binaphthyl with selenium followed by air oxidation gives a mixture of dinaph-thoselenophene and dimer and oligomers of 2, 2′-diseleno-1, 1′-binaphthyl. 2, 2′-Dilithio-1, 1′-biphenyl reacts with selenium to afford dibenzo [c, e][1, 2] diselenin. Structures of the dimeric 2, 2′-diseleno-1, 1′-binaphthyl and dibenzo [c, e][1, 2] diselenin have been confirmed by X-ray crystallographic analyses. Similar reaction of 2, ...
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