Phosphonic Systems. Part 10. Synthesis of 2-Hydroxyalkylphosphonic Diamides Via Opening of Epoxides with Diamidophosphite Anions

CP De Jongh, TA Modro

Index: Jongh, C. P. de; Zwierzak, A.; Modro, T.A. Phosphorus, Sulfur and Silicon and the Related Elements, 1991 , vol. 61, # 3.4 p. 205 - 209

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Abstract

Abstract Lithiated bis-dialkylamidophosphites react with mono-and 1, 2-disubstituted epoxides yielding 2-hydroxyalkylphosphonic diamides. Conformational analysis of the products revealed strong intramolecular attraction between the 2-hydroxy group and the P