Organoborane-catalyzed hydroalumination of olefins

K Maruoka, H Sano, K Shinoda, S Nakai…

Index: Maruoka, Keiji; Sano, Hiromi; Shinoda, Kiyotaka; Nakai, Shuichi; Yamamoto, Hisashi Journal of the American Chemical Society, 1986 , vol. 108, # 19 p. 6036 - 6038

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Citation Number: 33

Abstract

Among various hydrometalation reactions of olefins, hydroboration is far superior in view of the efficiency and versatility of the reaction.'However, the resulting organoboranes (CB bonds) are relatively stable and not readily functionalized compared to the corresponding organoaluminums (C-AI bonds) that possess more carbanion character and hence undergo facile intermolecular transfer reactions with a variety of organic and inorganic ...

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