Solvolyis reactions of perfluoro-5-aza-4-nonene, C 3 F 7 CF N C 4 F 9

…, RA Newmark, M Brostrom, DA Weil, K Erickson…

Index: Siedle; Webb, Robert J.; Newmark; Brostrom, Myles; Weil, David A.; Erickson, Kristin; Behr, Fred. E.; Young Jr., Victor G. Journal of Fluorine Chemistry, 2003 , vol. 122, # 2 p. 175 - 182

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Citation Number: 13

Abstract

Hydrolysis of the imine perfluoro-5-aza-4-nonene, C3F7 CF N C4F9, in ether was studied by several spectroscopic techniques including 17O NMR. The initial product is C3F7 CO NH C4F9 which is converted to (C3F7CO) 2NH and then to C3F7CONH2 and C3F7CO2H. Solvolysis in liquid ammonia afforded the amidine C3F7 C ( NH) NH2. Reaction with hydrazine produced 3, 5-bis (heptafluoropropyl)-1, 2, 4-triazole whose ...