The Journal of Organic Chemistry

Photochemical reaction of phthalimides and dicyanophthalimides with benzylic donors

M Freccero, E Fasani, A Albini

Index: Freccero, Mauro; Fasani, Elisa; Albini, Angelo Journal of Organic Chemistry, 1993 , vol. 58, # 7 p. 1740 - 1745

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Citation Number: 33

Abstract

Results The irradiation of an acetonitrile solution of phthaLimide (P) or N-methylphthalimide (NMP) and toluene (la), benzyltrimethyleilane (Ib), and diphenylmethane (IC) leads to the expected producte, viz. the hydroxyisoindolones 2a, c from P and 3a, c from NMP (Scheme I, Table I). As it is already known, in such producta the cyclic form predominates over the tautomeric open-chain ket~ amide.~'

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