Organometallics

Synthesis and crystal structure of ethyl zinc chloride

A Guerrero, DL Hughes, M Bochmann

Index: Guerrero, Antonio; Hughes, David L.; Bochmann, Manfred Organometallics, 2006 , vol. 25, # 6 p. 1525 - 1527

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Citation Number: 24

Abstract

Interest in alkyl zinc halides has existed for 150 years. Since Frankland's synthesis of EtZnI, 1 a multitude of applications have been found for such simple organometallic compounds in various fields of chemistry. For instance, alkylzinc iodides are used for Simmons−Smith cyclopropanation, 2 alkylzinc bromides are used for nickel-catalyzed Negishi reactions, 3 and EtZnCl generated in situ has been shown to be a good chain transfer agent in the ...