The Journal of Organic Chemistry

Substitution reactions of thallous thiophenoxide and thallous phenyl selenide with halogen-bearing substrates

MR Detty, GP Wood

Index: Detty, Michael R.; Wood, Gary P. Journal of Organic Chemistry, 1980 , vol. 45, # 1 p. 80 - 89

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Citation Number: 70

Abstract

Thallous thiophenoxide (1) and thallous phenyl selenide (2) were prepared by the action of either thallous ethoxide or thallous phenoxide on thiophenol and benzeneselenol. The reagents 1 and 2 reacted readily with aroyl and acyl halides, imidoyl chlorides, a-halo ketones, a-halo esters, a-halo lactones, a-halo carboxylic acids, allyl halides, alkyl halides, chlorotrimethylsilane, chloroacetonitrile, and N-chlorosuccinimide to give substitution ...

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