Heterocyclic analogs of pleiadiene 76. Synthesis and tautomeric conversions of mono-and disubstituted perimidines with electron-withdrawing substituents in the …

IV Borovlev, AF Pozharskii, EA Filatova…

Index: Borovlev; Pozharskii; Filatova; Demidov Chemistry of Heterocyclic Compounds, 2010 , vol. 46, # 3 p. 307 - 315

Full Text: HTML

Citation Number: 1

Abstract

A series of new mono- and disubstituted perimidines with electron-withdrawing substituents in the naphthalene fragment has been synthesized. Their prototropic annular tautomerism has been investigated by 1H NMR spectroscopy. ... Keywords: perimidine, PPA (polyphosphoric acid), annular prototropy, arenesulfonation, acylation. ... We reported previously on the extremely slow annular prototropic tautomerism of derivatives of 2-trifluoromethylperimidine ...