Stability constants of silver (I) complexes with diaza??18??crown ethers in polar solvents

T Burchard, BG Cox, P Firman…

Index: Burchard, T.; Cox, B. G.; Firman, P.; Schneider, H. Berichte der Bunsen-Gesellschaft, 1994 , vol. 98, # 12 p. 1526 - 1533

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Citation Number: 12

Abstract

Abstract The stability constants of Ag+ complexes with macrocyclic diaza-crown ethers of constant ring size [18], but with different donor atom distributions in the ligand bridges, are strongly dependent upon solvent. The effect of solvent, however, is essentially independent of the ligand involved, and this extends even to bicyclic cryptand ligands. Thus, the stability constants of any one ligand are linearly related to those of the other ligands across a wide ...