Tetrahedron Letters

Solvent-free chelation-assisted intermolecular hydroacylation: effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh (I) complex

CH Jun, JH Chung, DY Lee, A Loupy, S Chatti

Index: Jun, Chul-Ho; Chung, Jong-Hwa; Lee, Dae-Yon; Loupy, Andre; Chatti, Saber Tetrahedron Letters, 2001 , vol. 42, # 29 p. 4803 - 4805

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Citation Number: 39

Abstract

As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh (I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.

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