Reductive ring openings of glutarimides and barbiturates with sodium borohydride
Y Kondo, B Witkop
Index: Kondo,Y.; Witkop,B. Journal of Organic Chemistry, 1968 , vol. 33, # 1 p. 206 - 212
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Citation Number: 26
Abstract
XI, R= p-NOLCsHsCO XI1 (1024 a colorless oil, was also nitrogen free. The structure of the symmetric 0, O-diacetate X is supported by the nmr spectrum which showed a pair of triplets at 1.60 and 4.17 ppm (J= 7.5 cps) totaling eight protons in the characteristic arrangement-0- CH2-CH2-. The symmetric diacetate of 3-methyl-3-ethyl-l, 5-amylene glycol (X), on saponification with alcoholic potash, gave the diol IX, which was converted into the ...
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