Journal of fluorine chemistry

The synthesis and application of fluorous boronates without perfluorinated solvents

CY Wang, WD Meng, YG Huang, FL Qing

Index: Wang, Chun-Yan; Meng, Wei-Dong; Huang, Yan-Gen; Qing, Feng-Ling Journal of Fluorine Chemistry, 2005 , vol. 126, # 7 p. 996 - 1001

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Citation Number: 5

Abstract

The synthesis of a fluorous diol 4 bearing a perfluorodecyl chain was described. A series of boronic acid were attached to 4 by esterification. The purification of the products was fulfilled by facile filtration instead of expensive and environmental troublesome fluorous liquid–liquid extraction. The Suzuki cross-coupling reactions of the formed fluorous boronates 5 underwent smoothly and the fluorous diol 4 was recycled in good yields.

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