Phosphine oxide-functionalized polyfluorene derivatives: Synthesis, photophysics, electrochemical properties, and electroluminescence performance

…, ZL Zhou, LH Zhao, G Gibson, J Brug, S Lam…

Index: Guo, Zengshan; Liu, Deang; Wang, Cheng; Pei, Jian; Zhou, Zhanglin; Zhao, Lihua; Gibson, Gary; Brug, James; Lam, Sity; Mao, Samuel S. Science China Chemistry, 2011 , vol. 54, # 4 p. 678 - 684

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Abstract

Abstract A series of phosphine oxide-functionalized polyfluorene derivatives, PFH-PO-40-1 (P1), PFH-PO-20-1 (P2), PFH-PO-10-1 (P3), and PFH-PO-1-1 (P4), were prepared via a palladium-mediated Suzuki cross-coupling reaction. The structures and purities of all polymers were fully characterized by 1 H and 13 C NMR, UV-vis and photoluminescent spectroscopy, gel permeation chromatography, and TGA/DSC. Their emission features ...

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