Synthesis of novel heteromacrocyclic compounds from (E, E)-1, 2-diketone dioximes and dichloromethane

T Hosokawa, T Ohta, SI Murahashi

Index: Hosokawa, Takahiro; Ohta, Toshiyuki; Murahashi, Shun-Ichi Journal of the Chemical Society, Chemical Communications, 1982 , # 1 p. 7 - 8

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Abstract

Although a variety of macrocyclic polyether compounds such as crown ethers and cryptands have been reported in the literature,' there are few examples of heteromacrocycles con- taining oxime linkages except for Vogtle's macrocyclic mono- and di-oximes2 which are prepared from 1 ,Zdiketone dioximes and oligomeric dichloroethylene glycol by the usual methodY3 and a macrocyclic polyhydroximate formed via nucleophilic polymerization of acetonitrile ~xide.~ Described ...

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