Photochemistry of the nitrogen-thiocarbonyl systems. 2. Photochemistry of the thioimide systems: imide-thietanes

M Machida, K Oda, E Yoshida…

Index: Machida, Minoru; Oda, Kazuaki; Yoshida, Eiichi; Kanaoka, Yuichi Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1681 - 1688

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Citation Number: 33

Abstract

Results In the present work dithioimides were generally prepared by employing Lawesson's pr~ cedure.~ Dithiosuccinimides possess a low-intensity band in the UV spectra (EtOH) at around 410 nm (e-200), and a more intensive band near 320 nm (E-4 X lo4), assigned to be n,? r* and A, T*, respectively. 6 First, intramolecular hydrogen abstraction was tested with a series of N-alkyldithiosuccinimides 1 and 2, which were, after irradiation, recovered ...