PHOTOCHEMICAL REACTIONS OF METHYL DIAZOACETATE WITH POLYHALOMETHANES

WH Urry, JW Wilt

Index: Urry; Wilt Journal of the American Chemical Society, 1954 , vol. 76, p. 2594

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Citation Number: 21

Abstract

(1) WH Urrp and JR Eiszner, THIS JOURNAL, 74, 5822 (1952). over a period of eight hours. Products identified after distillation were methyl chloroacetate (5.55 g., 0.051 mole, bp 47- 52'at 18 mm.,%* OD 1.4660, mol. wt. Rast, 106, gave N-phenylglycine, mp 12702 when treated by the method of Koelsch3 in an attempt to form the anilide), and presumed methyl a, P, P-trichloropropionate (2.35 g., 0.02 mole, bp 85-90'at 18 mm., nZo~ 1.4626, mol. wt. ...