α-Fluorinated cyclic amidophosphite ligands. Their synthesis, Rh complexes and catalytic activity in the hydroformylation of styrene

O Artyushin, I Odinets, E Goryunov, I Fedyanin…

Index: Artyushin, Oleg; Odinets, Irina; Goryunov, Evgenii; Fedyanin, Ivan; Lyssenko, Konstantin; Mastryukova, Tatyana; Roeschenthaler, Gerd-Volker; Kegl, Tamas; Keglevich, Gyoergy; Kollar, Laszlo Journal of Organometallic Chemistry, 2006 , vol. 691, # 26 p. 5547 - 5559

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Citation Number: 13

Abstract

The synthetic approaches to cyclic phosphite and amido (diamido) phosphite ligands bearing the residues of electron withdrawing perfluorinated tails at the β-position to the phosphorus atom have been elaborated. Catalytic systems based on rhodium complexes of these ligands formed in situ using Rh (CO) 2 (acac) as a catalytic precursor demonstrate high activity in the hydroformylation of styrene along with good selectivity in respect to ...