A general synthesis of vinylic fluorides

…, RN Zuckermann, WS Johnson

Index: Daub, G. William; Zuckermann, Ronald N.; Johnson, William S. Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1599 - 1602

Full Text: HTML

Citation Number: 0

Abstract

A number of approaches to the vinylic fluoride moiety have been developed. They involve (1) the elimination of the elements of HF from a difluoro compound with alumina:(2) the reductive elimination of fluoride and halide from an a-halo gem-difluoride with a metal reducing agent, 1-13 (c) the ring opening of gem-chlorofluorocyclopropanes, 14 (d) the condensation reactions of aldehydes and ketones with fluorinated nu~ leophiles,~~ J~ ...

Related Articles:

Aromatic haloethylation with palladium and copper halides

[Heck,R.F. Journal of the American Chemical Society, 1968 , vol. 90, p. 5538 - 5542]

Separation of 2-Phenylethanol from Water by Liquid-Liquid Extraction with Ionic Liquids: New Experimental Data and Modeling with Modern Thermodynamic Tools

[Zampieri, Davila S.; De Paula, Bruno R.S.; Zampieri, Luiz A.; Vale, Juliana A.; Rodrigues, J. Augusto R.; Moran, Paulo J.S. Journal of Molecular Catalysis B: Enzymatic, 2013 , vol. 85-86, p. 61 - 64]

Metal-catalyzed organic photoreactions. One-step synthesis of chlorinated ketones from olefins by photooxidation in the presence of iron (III) chloride

[Kohda, Akira; Ueda, Keiko,; Sato, Tadashi Journal of Organic Chemistry, 1981 , vol. 46, # 3 p. 509 - 515]

Hydride transfer versus electron transfer in the reduction of 4-phenyl-3-halo-3-buten-2-ones mediated by Pichia stipitis

[Zampieri, Davila S.; Zampieri, Luiz A.; Rodrigues, J. Augusto R.; De Paula, Bruno R.S.; Moran, Paulo J.S. Journal of Molecular Catalysis B: Enzymatic, 2011 , vol. 72, # 3-4 p. 289 - 293]

Reaktionen mit phosphororganischen verbindungen—XXI: Eine neuartige darstellungsweise von unsymmetrischen α-chlorketonen

[Zbiral,E.; Rasberger,M. Tetrahedron, 1969 , vol. 25, p. 1871 - 1874]

More Articles...