Fast Olefin Metathesis at Low Catalyst Loading

LH Peeck, RD Savka, H Plenio

Index: Peeck, Lars H.; Savka, Roman D.; Plenio, Herbert Chemistry - A European Journal, 2012 , vol. 18, # 40 p. 12845 - 12853

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Citation Number: 27

Abstract

Abstract Reactions of the Grubbs 3rd generation complexes [RuCl 2 (NHC)(Ind)(Py)](N- heterocyclic carbene (NHC)= 1, 3-bis (2, 4, 6-trimethylphenylimidazolin)-2-ylidene (SIMes), 1, 3-bis (2, 6-diisopropylphenylimidazolin)-2-ylidene (SIPr), or 1, 3-bis (2, 6- diisopropylphenylimidazol)-2-ylidene (IPr); Ind= 3-phenylindenylid-1-ene, Py= pyridine) with 2-ethenyl-N-alkylaniline (alkyl= Me, Et) result in the formation of the new N-Grubbs– ...

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