Journal of Organometallic Chemistry

An eco-friendly procedure for the efficient synthesis of dialkyl α-aminophosphonates in aqueous media

S Sobhani, E Safaei, M Asadi, F Jalili

Index: Sobhani, Sara; Safaei, Elham; Asadi, Mozaffar; Jalili, Fariba Journal of Organometallic Chemistry, 2008 , vol. 693, # 21-22 p. 3313 - 3317

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Citation Number: 61

Abstract

A new, convenient and high yielding procedure for the preparation of diethyl α- aminophosphonates in water by one-pot reaction of aldehydes, amines, tri/dialkyl phosphites in the presence of a low catalytic amount of [Cu (3, 4-tmtppa)](MeSO4) 4 (0.16 mol%) as a highly stable and re-usable catalyst is described.

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