Molecular studies of the initiation and termination steps of the anionic polymerization of P= C bonds

BH Gillon, KJT Noonan, B Feldscher…

Index: Gillon, Bronwyn H.; Noonan, Kevin J.T.; Feldscher, Bastian; Wissenz, Jennifer M.; Kam, Zhi Ming; Hsieh, Tom; Kingsley, Justin J.; Bates, Joshua I.; Gates, Derek P. Canadian Journal of Chemistry, 2007 , vol. 85, # 12 p. 1045 - 1052

Full Text: HTML

Citation Number: 11

Abstract

The initiation and termination steps of the anionic polymerization of P= C bonds have been modeled. The initiation step was investigated through the stoichiometric reaction of MesP= CPh2 (1) with RLi (R= Me or n-Bu). In each case, the addition was highly regioselective with the formal attack of R-at phosphorus to give the carbanion Li [Mes (R) P-CPh2](3a, R= Me; 3b, R= n-Bu). To simulate the termination step in the anionic polymerization of 1, ...

Related Articles:

Solid-phase chemical synthesis of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides

[Dellinger, Douglas J.; Sheehan, David M.; Christensen, Nanna K.; Lindberg, James G.; Caruthers, Marvin H. Journal of the American Chemical Society, 2003 , vol. 125, # 4 p. 940 - 950]

Selective synthesis of chlorophosphoramidites using ionic liquids

[Green Chemistry, , vol. 11, # 9 p. 1391 - 1396]

Reaction of Bis (chloromethyl) phosphinoyl Chloride and Phenyl (Chloromethyl) phosphonochloridate with Diethyl Bis (trimethylsilyl) phosphoramidite

[Russian Journal of General Chemistry, , vol. 73, # 1 p. 151 - 152]

More Articles...