Organometallic chemistry under high pressure: trialkyltin hydride addition to unsaturated systems

A Rahm, M Degueil-Castaing, M Pereyre

Index: Rahm, A.; Castaing-Degueil, M.; Pereyre, M. Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. C29 - C32

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Citation Number: 10

Abstract

Abstract The influence of high pressure (10–14 kbars) on the reaction of tin hydrides with alkenes and ketones has been investigated and a marked increase of yields generally was observed. For cyclopropyl-and cyclobutyl-alkenes, adducts were formed with retention of the rings. The stereochemical outcomes of the reactions were modified.

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