Tetrahedron

Palladium-catalysed cross-coupling reactions of arylboronic acids with π-deficient heteroaryl chlorides

…, A McKillop, MB Mitchell, RA Rebelo, PJ Wallbank

Index: Ali; McKillop; Mitchell; Rebelo; Wallbank Tetrahedron, 1992 , vol. 48, # 37 p. 8117 - 8126

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Citation Number: 132

Abstract

The palladium-catalysed cross-coupling reactions of arylboronic acids with a variety of π- deficient heteroaryl chlorides proceed in high yield.[1, 4-Bis (diphenylphosphino) butane] palladium (II) dichloride was found to be a very satisfactory catalyst for monocyclic heteroaryl chlorides, whereas tetrakis (triphenylphosphine) palladium (O) was found to be excellent for a range of chloroquinoline derivatives.

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