Biomimetic Oxidation Studies. 11. Alkane Functionalization in Aqueous Solution Utilizing in Situ Formed [Fe2O (η1-H2O)(η1-OAc)(TPA) 2] 3+, as an MMO Model …

K Neimann, R Neumann, A Rabion…

Index: Neumann, Ronny; Wang, Tie-Jun Chemical Communications, 1997 , # 19 p. 1915 - 1916

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Citation Number: 31

Abstract

The biomimetic, MMO precatalyst,[Fe2O (η1-H2O)(η1-OAc)(TPA) 2] 3+(TPA= tris [(2-pyridyl) methyl] amine), formed in situ at pH 4.2, was embedded in an amorphous silicate surface modified by a combination of hydrophilic poly (ethylene oxide) and hydrophobic poly

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