Selective hydrogenation of cyclopentadiene to cyclopentene using colloidal palladium supported on chelate resin.

H Hirai, S Komatsuzaki, N Toshima

Index: Hirai; Komatsuzaki; Toshima Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 2 p. 488 - 494

Full Text: HTML

Citation Number: 36

Abstract

Cyclopentadiene was hydrogenated to cyclopentene selectively by using colloidal palladium supported on chelate resin with iminodiacetic acid moieties as a catalyst. The catalyst, containing metal particles of 1–6 nm in diameter, was prepared by reduction of the palladium (II)–chelate resin complex with methanol. Cyclopentene was produced in 97.1% yield at 100% conversion of cyclopentadiene at 30° C under 1 atm of hydrogen. This value ...

Related Articles:

An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation

[Arceo, Elena; Marsden, Peter; Bergman, Robert G.; Ellman, Jonathan A. Chemical Communications, 2009 , # 23 p. 3357 - 3359]

Kinetics and mechanism of rhenium-catalyzed O atom transfer from epoxides

[Isobe, Hiroshi; Branchaud, Bruce P. Tetrahedron Letters, 1999 , vol. 40, # 50 p. 8747 - 8749]

Trapping of free alkyl radical intermediates in the reaction of alkyl bromdies with magnesium

[Journal of the American Chemical Society, , vol. 102, # 7 p. 2493 - 2494]

Cyclization and dehydrocyclization of C 5 hydrocarbons over platinum nanocatalysts and in the presence of hydrogen sulfide

[Doklady Chemistry, , vol. 424, # 2 p. 27 - 30]

New deaminations IX-pyrolysis of N-alkyl-N, N-disulfonimides

[Tetrahedron Letters, , vol. 22, p. 199 - 202]

More Articles...