Tetrahedron letters

Oxidation of enol ethers by metal (vi) oxide diperoxides

R Curci, L Lopez, L Troisi, SMK Rashid, AP Schaap

Index: Curci, Ruggero; Lopez, Luigi; Troisi, Luigino; Rashid, S. M. Khaledur; Schaap, A. Paul Tetrahedron Letters, 1988 ,  vol. 29,  # 25  p. 3145 - 3148

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Citation Number: 13

Abstract

Abstract Alkoxy (aryl) adamantylidenes react with chromium (VI) or molybenum (VI) oxide diperoxides in CHCl 3 under argon yielding the corresponding 1, 2-dioxetanes and/or carbonyl products derived from the fragmentation of the dioxetanes. The reaction most likely proceeds via preliminary epoxidation of the unsaturaled substrates.

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