The cyanation of aromatic halides catalyzed by nickel (0) complexes generated in situ. I. General scope and limitations.

…, F Okuda, A Shimobayashi, K Kirino, M Sakai…

Index: Sakakibara, Yasumasa; Okuda, Fumio; Shimobayashi, Akira; Kirini, Kunihiko; Sakai, Mutsuji; et al. Bulletin of the Chemical Society of Japan, 1988 , vol. 61, p. 1985 - 1990

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Citation Number: 80

Abstract

The cyanation of chlorobenzene catalyzed by Ni (PPh 3) n, which was generated in situ from NiBr 2 (PPh 3) 2–Zn–PPh 3 (Ni: Zn: P= 1: 3: 2 molar ratio), was at first examined with various MCN (M= K, Na)–solvent systems by three procedures in order to clarify the conditions under which the reaction occurs. The effects of the systems and the procedures on the reaction were remarkable. It was observed that the cyanide ion has an inhibitory action on ...

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