Acid??, Water??and High??Temperature??Stable Ruthenium Complexes for the Total Catalytic Deoxygenation of Glycerol to Propane

…, ME Thibault, D Di Mondo, M Jennings…

Index: Taher, Deeb; Thibault, Michelle E.; Di Mondo, Domenico; Jennings, Michael; Schlaf, Marcel Chemistry - A European Journal, 2009 , vol. 15, # 39 p. 10132 - 10143

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Citation Number: 46

Abstract

Abstract The ruthenium aqua complexes [Ru (H 2 O) 2 (bipy) 2](OTf) 2,[cis-Ru (6, 6′-Cl 2- bipy) 2 (OH 2) 2](OTf) 2,[Ru (H 2 O) 2 (phen) 2](OTf) 2,[Ru (H 2 O) 3 (2, 2′: 6′, 2′′- terpy)](OTf) 2 and [Ru (H 2 O) 3 (Phterpy)](OTf) 2 (bipy= 2, 2′-bipyridine; OTf−= triflate; phen= phenanthroline; terpy= terpyridine; Phterpy= 4′-phenyl-2, 2′: 6′, 2′′- terpyridine) are water-and acid-stable catalysts for the hydrogenation of aldehydes and ...

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