Organometallics

Lewis Acid Catalysis with Cationic Dinuclear Gold (II, II) and Gold (III, III) Phosphorus Ylide Complexes

BR Reiner, MW Bezpalko, BM Foxman…

Index: Lin, Ji-Mao; Liu, Ben-Sheng Synthetic Communications, 1997 , vol. 27, # 5 p. 739 - 749

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Abstract

... The 31 P{ 1 H} NMR spectrum of 3-OTf 2 in CD 3 CN displays a single resonance at 35.1 ppm, shifted slightly upfield from ... Figure 2). Analysis of the first-order rate plots revealed initial observed rate constants (k obs ) of 1.1 × 10 –3 and 8.4 × 10 –5 s –1 ... 1, 2-OTf 2, 4%, 5a, 68, 27. ...

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