Thermolyses and reactions with nucleophiles of N-sulfur-group-substituted sulfoximines

S Oae, K Akutagawa, N Furukawa

Index: Oae, Shigeru; Akutagawa, Kunihiko; Furukawa, Naomichi Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 223 - 234

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Abstract

Abstract Thermolyses and reactions with nucleophiles of S, S-diphenylsulfoximines (1) bearing the following N-sulfur-substituents, ie, Np-tolylthio-(b), Np-tolylsulfinyl-(c), N-(N′-p- tolylsulfonyl-p-toluenesulfinimidoyl)-(d), N-(S′, S′-diphenylsulfonio)-(e), Np-tolylsulfonyl- (f), and N-(N′-p-tolylsulfonyl-p-toluenesul-fonimidoyl)-(g), have been examined. The former three sulfoximines (1b-d) are thermally unstable and readily decompose to form diphenyl ...

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