Tetrahedron Letters

Synthesis and structural characterization of palladium (II) thiosemicarbazone complex: application to the Buchwald–Hartwig amination reaction

RN Prabhu, R Ramesh

Index: Prabhu, Rupesh Narayana; Ramesh, Rengan Tetrahedron Letters, 2013 , vol. 54, # 9 p. 1120 - 1124

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Citation Number: 25

Abstract

A simple route to synthesize mononuclear palladium (II) thiosemicarbazone complex has been described. Elemental analysis, spectral methods and single crystal X-ray diffraction analysis were used to confirm the composition of the complex. The new complex acts as an active homogeneous catalyst for the Buchwald–Hartwig amination reaction of a wide range of aryl and heteroaryl halides (bromides and chlorides), including activating, neutral and ...

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