Synthetic Communications

Oxidative Deprotection of Oximes Using Pyridinium Fluorochromate and Hydrogen Peroxide

NC Ganguly, AK Sukai, S De, P De

Index: Ganguly; Sukai; De Synthetic Communications, 2001 , vol. 31, # 10 p. 1607 - 1612

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Citation Number: 21

Abstract

A simple convenient procedure of oxidative deoximation has been developed using pyridinium fluorochromate (PFC), in combination with 30% hydrogen peroxide. The method has been found to be effective for a wide range of aliphatic and aromatic oximes, and may be used for selective cleavage of aldoximes in the presence of ketoximes.

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