Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions

AI Ilovaisky, VM Merkulova, YN Ogibin…

Index: Ilovaisky; Merkulova; Ogibin; Nikishin Russian Chemical Bulletin, 2005 , vol. 54, # 7 p. 1585 - 1592

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Abstract

Abstract Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1-and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH 2 Cl 2/H 2 O) produces geminal nitrohalides (35–85% yields), dinitro compounds (15–51%), nitronitriles (6–27%), and ...

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