Synthesis and properties of doped. mu.-oxo (tetrabenzoporphyrinato) germanium (IV)

M Hanack, T Zipplies

Index: Hanack, Michael; Zipplies, Tilman Journal of the American Chemical Society, 1985 , vol. 107, # 21 p. 6127 - 6129

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Citation Number: 23

Abstract

TBPH,(2) was accomplished with trifluoroacetic acid in chloroform. 20 TBPHz (2) was converted to TBPGeCl,(3) by a modification of the reportedz1 procedure by reacting 2 with GeC14 in refluxing quinoline. TBPGe (OH)*(4) was obtained from 3 by hydrolysis in quinoline containing 1 N KOH (2: l). Thermal dehydration of 4 at 350 OC torr) gave the polymer 5 in an overall yield of 47% based on TBPZn. The intermediate products 3 and 4 ...