Reactions of organochlorosilanes with chloro-and organogermanes in the presence of aluminum chloride

IV Sbitneva, AN Polivanov, EA Chernyshev

Index: Zhun; Sbitneva; Polivanov; Chernyshev Russian Journal of General Chemistry, 2006 , vol. 76, # 10 p. 1564 - 1570

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Abstract

Abstract The effect of substituents at the silicon and germanium atoms in reactions of organochlorosilanes with chloro-and organogermanes in the presence of aluminum chloride was studied. The only occurring process is the exchange of the chlorine atoms at Ge for the phenyl groups from Si; an increase in the number of methyl groups or chlorine atoms at Si promotes formation of phenyltrichlorogermane, and an increase in the number of phenyl ...

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