Inorganic Chemistry

Synthesis and spectroscopic characterization of (triethylphosphine) gold (I) complexes AuX (PEt3)(X= Cl, Br, CN, SCN),[AuL (PEt3)+](L= SMe2, SC (NH2) 2, H2O), and …

MM El-Etri, WM Scovell

Index: El-Etri, M. M.; Scovell, W. M. Inorganic Chemistry, 1990 , vol. 29, p. 480 - 484

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Citation Number: 43

Abstract

Neutral complexes of the type AuX (PEt,)(X= Br, CN, SCN) were prepared and characterized by infrared and Raman spectroscopy, with the major emphasis on the assignment of the gold-ligand vibrations and discerning the mode of bonding for the ambidentate ligands. The photosensitive cationic complexes [(Au (SMe2)(PEt,)] PF6 and {Au [SC (NH~)~](PE~,)~ CI in addition to [Au (OH,)(PEt,)] NO, and (pS)[(PEt,) Au], were also prepared and characterized ...

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