Tetrahedron

Synthesis and structural studies of some gold (I) complexes containing selenoureato ligands

A Molter, J Rust, CW Lehmann, F Mohr

Index: Molter, Anja; Mohr, Fabian; Rust, Joerg; Lehmann, Christian W. Tetrahedron, 2012 , vol. 68, # 51 p. 10586 - 10591,6

Full Text: HTML

Citation Number: 10

Abstract

N, N-Diethyl-N′-4-nitrobenzoylselenourea (HLSe) reacts with the mono-and dinuclear phosphine gold (I) chloro complexes [AuCl (PR3)](R= Ph, o-tol, Et) and [Au2Cl2 (μ-PP)](PP= dppm, dppe, dppp, dppb, dppf) in the presence of base to give gold (I) phosphine selenoureato complexes [Au (LSe)(PR3)][R= Ph (1), o-tol (2), Et (3)],[Au2 (LSe) 2 (μ- PP)][PP= dppm (4), dppe (5), dppp (6), dppb (7), dppf (8)] in excellent yields. The ...

Related Articles:

Preparation and Structure of Hexakis [(trialkylphosphane) aurio (I)] methanium (2+) Salts [(LAu) 6C] 2+(X??) 2 with L Et3P, iPr3P and X BF4??, B3O3F4??

[Schmidbaur, Hubert; Brachthaeuser, Benno; Steigelmann, Oliver; Beruda, Holger Chemische Berichte, 1992 , vol. 125, # 12 p. 2705 - 2710]

Synthesis and spectroscopic characterization of (triethylphosphine) gold (I) complexes AuX (PEt3)(X= Cl, Br, CN, SCN),[AuL (PEt3)+](L= SMe2, SC (NH2) 2, H2O), and …

[El-Etri, M. M.; Scovell, W. M. Inorganic Chemistry, 1990 , vol. 29, p. 480 - 484]

More Articles...