Journal of the American Chemical Society

1, 5 PARTICIPATION IN THE SOLVOLYSIS OF β-(Δ3-CYCLOPENTENYL)-ETHYL p-NITROBENZENESULFONATE

RG Lawton

Index: Lawton,R.G. Journal of the American Chemical Society, 1961 , vol. 83, p. 2399

Full Text: HTML

Citation Number: 46

Abstract

R= H) was prepared as described by alkylation of ethyl cyaiioacetate with A3-cyclopentenyl tosylate5 and afforded a 60% yield of ethyl a-cyano-a-(A3-cyclopentenyl) acetate, 6 bp 143'(16 mm.), n2b 1.4584, N-benzylamide, mp 115-116', which upon hydrolysis with 50yo aqueous ethanolic potassium hydroxide produced A3-cyclopentenylmalonic acid, mp 149- 150'dec., in 90% yield. Decarboxylation of the malonic acid in refluxing pyridine gave A3- ...

Related Articles:

Oxygenation of aromatic and aliphatic hydrocarbons by a new reagent system, Fe (CH3CN) 62+-H2O2-Ac2O: An effective model reagent for mono-oxygenase.

[Kotani, Eiichi; Kobayashi. Shigeki; Ishii, Yoko; Tobinaga, Seisho Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 11 p. 4671 - 4679]

Aliphatische Azoverbindungen, I Darstellung und Thermolyse von 1.1′??Dimethyl??azocycloalkanen, 1??Methylcycloalkyl??azobenzolen und 1??Methylcycloalkyl??azo?螃窿? …

[Komppa; Beckmann Justus Liebigs Annalen der Chemie, 1934 , vol. 512, p. 172,182]

2-Norbornanediazonium ions revisited

[Kirmse, Wolfgang; Siegfried, Rainer Journal of the American Chemical Society, 1983 , vol. 105, # 105 p. 950 - 956]

2-Norbornanediazonium ions revisited

[Kirmse, Wolfgang; Siegfried, Rainer Journal of the American Chemical Society, 1983 , vol. 105, # 105 p. 950 - 956]

The protonated cyclopropane route to bicyclic cations

[Kirmse, Wolfgang; Streu, Joachim Journal of Organic Chemistry, 1987 , vol. 52, # 4 p. 515 - 521]

More Articles...