Dehydrogenation of amines to nitriles in aqueous micelles

D Biondini, L Brinchi, R Germani…

Index: Biondini, Daniele; Brinchi, Lucia; Germani, Raimondo; Goracci, Laura; Savelli, Gianfranco European Journal of Organic Chemistry, 2005 , # 14 p. 3060 - 3063

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Citation Number: 26

Abstract

Abstract An aqueous reaction medium, based on a surfactant solution of dimethyldodecylamine N-oxide (DDAO) has been developed for the oxidative dehydrogenation of primary amines using NiSO 4 as catalyst and K 2 S 2 O 8 as oxidant. This reaction medium enhances the rate of the reaction relative to other media previously reported in the literature, which are also toxic. The reactions of various aliphatic and cyclic ...

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