Mechanism of formation of organic carbonates from aliphatic alcohols and carbon dioxide under mild conditions promoted by carbodiimides. DFT calculation and …

M Aresta, A Dibenedetto, E Fracchiolla…

Index: Journal of Organic Chemistry, , vol. 70, # 16 p. 6177 - 6186

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Citation Number: 64

Abstract

... The Journal of Organic ... J. Org. ... DCC reacts with aliphatic alcohols to produce O-alkyl isoureas according to eq 2. The latter is a quite effective agent for the conversion of organic acids into the relevant alkylesters 17 at room temperature and of phenols into their ethers at380 K ...

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