Journal of the American Chemical Society

Photohydration of styrenes and phenylacetylenes. General acid catalysis and Broensted relationships

J McEwen, K Yates

Index: McEwen, John; Yates, Keith Journal of the American Chemical Society, 1987 , vol. 109, # 19 p. 5800 - 5808

Full Text: HTML

Citation Number: 32

Abstract

Abstract: The acid-catalyzed photohydrations of a series of substituted styrenes and phenylacetylenes have been investigated in aqueous buffer solutions. General acid catalysis was clearly detected in five cases with a range of catalysts, and approximately linear Brernsted plots gave a values in the range 0.14-0.18. The rate enhancements caused by excitation from So to S, were estimated from comparisons with thermal hydration data ...

Related Articles:

Ruthenium (II) complex catalysts bearing a pyridyl-supported pyrazolyl-imine ligand for transfer hydrogenation of ketones

[Zhao, Miao; Yu, Zhengkun; Yan, Shenggang; Li, Yang Journal of Organometallic Chemistry, 2009 , vol. 694, # 19 p. 3068 - 3075]

Regioselective hydroboration-oxidation and-amination of fluoro-substituted styrenes

[Ramachandran, P. Veeraraghavan; Madhi, Sateesh; O'Donnell, Martin J. Journal of Fluorine Chemistry, 2006 , vol. 127, # 9 p. 1252 - 1255]

Cerium (III) bromate as a new reagent in oxidation of organic compounds

[Shaabani, Ahmad; Lee, Donald G. Synthetic Communications, 2003 , vol. 33, # 11 p. 1845 - 1854]

QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY

[Li, Jia; Wang, Chao; Xue, Dong; Wei, Yawen; Xiao, Jianliang Green Chemistry, 2013 , vol. 15, # 10 p. 2685 - 2689]

Asymmetric transesterification of secondary alcohols catalyzed by feruloyl esterase from Humicola insolens

[Hatzakis, Nikos S.; Smonou, Ioulia Bioorganic Chemistry, 2005 , vol. 33, # 4 p. 325 - 337]

More Articles...